Bis(pyridinium) trans-tetrachloridodioxidouranate(VI) dioxane solvate
نویسندگان
چکیده
In the crystal structure of the title compound, (C(5)H(6)N)(2)[UCl(4)O(2)]·C(4)H(8)O(2), the pyridinium cations occupy general positions and the anions and the solvent dioxane mol-ecule are located on centres of inversion. The dioxane mol-ecules are connected to two symmetry-related pyridinium cations via O-H⋯O hydrogen bonding. There are additional inter-molecular C-H⋯Cl contacts, which are indicative of weak C-H⋯Cl inter-actions.
منابع مشابه
Conformational behaviors of trans-2,3-bis(methylthio)-1,4-dioxane, -dithiane and –diselenane. A hybrid-DFT study and NBO interpretations
The conformational behaviors of 2,3-bis(methylthio)-1,4-dioxane (1), 2,3-bis(methylthio)-1,4-dithiane (2) and 2,3-bis(methylthio)-1,4-diselenane (3) have been analyzed by means ofhybrid-density functional theory (B3LYP/Def2-TZVPP) based method and NBO interpretation.B3LYP/Def2-TZVPP results showed that the axial conformations of compounds 1-3 are morestable than their equatorial conformations. ...
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